Effect of modified layered silicates and compatibilizer on properties of PMP/clay nanocomposites

The preparation and properties of poly(4‐methyl‐1‐pentene) (PMP)/clay nano‐composites are described for the first time. The effect of clay modification and compatibilizer on the formation and properties of the nanocomposites is studied. Layered silicates modified with two types of quaternary ammonium salts are used. The X‐ray diffraction results indicate intercalation of the polymer into the intergallery spacing of the clay. Thermogravimetric analysis shows a delay in the degradation process. Dynamic mechanical analysis shows an increase in the storage modulus for the nanocomposites. The use of compatibilizer containing maleic anhydride and acrylic ester groups is explored. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3233–3238, 2003     

Microstructure of high modulus solid state extruded polyethylene: 2. X-ray scattering studies of 12, 24 and 36 extrusion draw ratio

The microstructure of a series of solid state extruded polyethylene fibres was examined by wide- and small-angle X-ray scattering. By measuring absolute intensities using a two dimensional position sensitive detector, accurate values of the small-angle invariant for anisotropic samples were obtained. This measurement coupled with wide-angle X-ray scattering and d.s.c. permitted determination of the density of the noncrystalline component. The use of a two phase model for solid state extruded polyethylene is justified if consideration is given to the effective densities of the crystalline and noncrystalline phases, which change with deformation. The effective density of the crystalline phase decreases by 1% (0.999–0.990 g cm^?3) from the unextruded billet compared to a 36 draw ratio extrudate, while the noncrystalline phase density increases by 6% (0.84–0.89 g cm^?3). These changes lead to an overall decrease in the mean squared electron density fluctuation of 63%. The average axial crystallite length measured by wide-angle X-ray scattering increases with extrusion draw ratio while the SAXS long period decreases and weakens considerably. These observations and the electron microscopy results from the previous paper, (Polymer, 1982, 23, 1069), are fully consistent with the key features of the Peterlin model of fibre microstructure.     

防火弹性涂料在硅酸铝耐火绳上的应用

介绍了防火弹性涂料(HT04—00)的组成和它的性能，在硅酸铝耐火绳上刷涂防火弹性涂料后的技术性能指标，以及它的施工工艺。     

弹性四连杆机构动力学响应的数值求解

针对弹性四连杆机构这一非线性动力学系统,采用直接积分法中的Wilson-θ法对弹性四连杆机构的动力学响应进行求解.同时对其进行了相应的实验研究,通过仿真与实验对比,验证了Wilson-θ法求解非线性动力学模型的可行性.     

飞机水平盘旋下弹性支承转子的特性研究

为研究转子系统在一定的外激励下的特性,使得研究与实际状况更加吻合,采用Jeffcott转子弹性支承模型,建立飞机处于水平盘旋状态下弹性支承转子系统的运动微分方程.运用Runge-Kutta数值法研究了飞机水平盘旋下处于一定角速度的刚性和弹性不同支承情况下的瞬态响应,并对仿真结果进行对比分析.结果表明,由于弹性支承使其转轴刚度降低,其临界转速随之降低;处于同一角速度下的弹性支承比刚性支承进入稳定振动的时间长,比刚性支承振动幅度大;弹性支承和刚性支承在同样的情况下转动都会产生稳定的周期解;因此可以通过对转子系统支承刚度的适当调节,可以达到优化系统性能的目的.     

Experimental study on temperature stress calculation and temperature control optimization of concrete based on early age parameters

Temperature control curve is the key to achieving temperature control and crack prevention of high concrete dam during construction,and its rationality depends on the accurate measurement of temperature stress.With the simulation testing machine for the temperature stress,in the present study,we carried out the deformation process tests of concrete under three temperature curves：convex,straight and concave.Besides,we not only measured the early-age elastic modulus,creep parameters and stress process,but also proposed the preferred type.The results show that at early age,higher temperature always leads to greater elastic modulus and smaller creep.However,the traditional indoor experiments have underestimated the elastic modulus and creep development at early age,which makes the calculated value of temperature stress too small,thus increasing the cracking risk.In this study,the stress values of the three curves calculated based on the strain and early-age parameters are in good agreement with the temperature stress measured by the temperature stress testing machine,which verifies the method accuracy.When the temperature changes along the concave curve,the law of stress development is in consistent with that of strength.Under this condition,the stress fluctuation is small and the crack prevention safety of the concave type is higher,so the concave type is better.The test results provide a reliable basis and support for temperature control curve design and optimization of concrete dams.     

Thermal expansion of an SiC particle-reinforced aluminum composite

Using a push-rod dilatometer, we measured between 76 and 390 K the thermal expansion of a particle-reinforced-composite wrought plate obtained by powdermetallurgy methods. The particles, 30% by volume, consisted of monocrystals of -SiC with sizes near 10 m. The matrix consisted of a 6061 aluminum alloy with original particle sizes near 20 m. We found the perpendicular thermal expansivity, ₃, higher by 26% than the in-plane thermal expansivity, ₁-₂. These values differ from a rule-of-mixture prediction by –3 and –23%, respectively. All three _i, components lie outside the Rosen-Hashin bounds. Levin's isotropic model agrees within 10% with the ₁-₂-₃ average. Both the anisotropy and the bounds violation result from microstructural nonhomogeneity arising from processing. Rosen and Hashin's transverse-isotropicsymmetry relationships account approximately for these effects by introducing the anisotropic elastic constants. Using neutron diffraction, we determined that the SiC particles are textureless.Paper presented at the Tenth International Thermal Expansion Symposium, June 6–7, 1989, Boulder, Colorado, U.S.A.     

基于弹性网络模型的蛋白质结构-功能关系

蛋白质结构-功能关系研究是结构生物学领域的热点问题之一,具有重要的理论和实际应用价值.弹性网络模型(elastic network model,ENM)是获取蛋白质结构本身固有动力学性质,进而揭示其生物学功能的有效方法,在蛋白质结构-功能关系研究中得到了广泛应用.简要介绍了ENM的基本原理及其在蛋白质结构-功能关系中的应用,主要包括蛋白质功能性运动分析和关键位点识别等.     

蛋白质折叠的计算机模拟研究进展

蛋白质折叠是结构生物学领域有待解决的重要科学问题,计算机模拟方法是研究蛋白质折叠的主要手段之一.对蛋白质折叠的计算机模拟研究进展进行了简要介绍,主要内容包括:全原子分子动力学模拟、Gō模型以及弹性网络模型的主要思路及其在蛋白质折叠研究中的应用.     

某超高层框筒结构的抗震性能分析

本文以某超限框架-核心筒结构为例,通过对该结构在多遇地震下的弹性分析、设防烈度下的等效弹性计算以及罕遇地震下等效弹性分析和弹塑性分析,并对开洞楼层的楼板应力分析,检验其抗震性能。分析结果表明,通过加强措施后,能达到期望的性能目标,可供同类工程参考。